Whereas, in the NFL, teams hope to win the coin toss and win the game at the first time of asking, in the collegiate game, the team that wins the toss usually decides to go on defense first because they will know if the other team scored a touchdown, a field goal or failed to score. Based on that, the team that goes second can choose to be more or less aggressive when they get on offense.
Source: CNN January 24, 2022 16:06 UTC