Angelina Jolie and Brad Pitt were one of the most powerful celebrity couples of all time. Jolie shared how she came to know Pitt when they got together to shoot the 2005 film, Mr. & Mrs. Smith. The Gia star before openly accepting her relationship with Pitt hinted at their love by stating that she usually falls in love while working on a film. Jolie stated that working on the Mr. & Mrs. Smith together with Pitt gave her an opportunity to get understand him well. Mr. & Mrs. Smith is available on Amazon Prime Video.
